Crystal structure of tris(N-methylsalicylaldiminato-κ2 N,O)vanadium(III)
نویسندگان
چکیده
The structure of the title complex, [V(C8H8NO)3], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl-alicylaldiminate ligands within a slightly distorted mer-N3O3 octa-hedral geometry. In the crystal structure, the mol-ecules are linked via C-H⋯O hydrogen bonds into supra-molecular chains that extend along the c axis.
منابع مشابه
Crystal structure of tris(N-methylsalicylaldiminato-κ2 N,O)chromium(III)
The crystal structure of the title compound, [Cr(C8H8NO)3], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr(3+) cation and three N-methyl-salicylaldiminate anions. The metal cation is octa-hedrally coordinated by three N,O-chelating N-methyl-salicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked...
متن کاملBis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ2 N 2′,O]tris(nitrato-κ2 O,O′)praseodymium(III)
In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-anti-prismatic geometry. An extensive three-dimensional network of weak inter-molecular C-H⋯O hydrogen bonds consolidates the ...
متن کاملBis(2,2′-bipyridine-κ2 N,N′)tris(nitrato-κ2 O,O′)erbium(III)
The asymmetric unit of the title compound, [Er(NO(3))(3)(C(10)H(8)N(2))(2)], contains one-half mol-ecule situated on a twofold rotation axis. The Er(III) ion is in a tenfold coordination by six O atoms from three NO(3) (-) anions and four N atoms from two 2,2'-bipyridine ligands in a distorted bicapped dodeca-hedral geometry. In the crystal, weak C-H⋯O hydrogen bonds hold the mol-ecules together.
متن کاملBis{[6-methoxy-2-(4-methylphenyl)iminiomethyl]phenolate-κ2 O,O′}tris(nitrato-κ2 O,O′)europium(III)
The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth-oxy-2-[(4-methyl-phen-yl)imino-meth-yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu-O(deprotonated phenolate) bond and a weak Eu-O(...
متن کاملTris(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III)–(nitrato-κ2 O,O′)bis(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III) (1/1)
The title co-crystal, [Eu(NCS)3(C18H15OP)3][Eu(NCS)2(NO3)(C18H15OP)3], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol-ecule contains disorder of its bidentate nitrate and two N-bound thio-cyanate anions, while the [Eu(NCS)3(OPPh3)3] complex is fully ordered. There is a weak π-π stacking inter-act...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015